Electron Spin-Spin Interaction and Translational Diffusion of Nitroxide Radicals in Sodium Dodecyl Sulfate Micelles
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چکیده
منابع مشابه
Growth of Sodium Dodecyl Sulfate Micelles with Detergent Concentration
Sodium alkyl sulfate micelles are predicted to grow as a power law of the total counterion salt concentration, Yaq, in the aqueous phase as follows: NA = K~(Y~~)Y, where N A is the micelle aggregation number and ~2 and y are constants which are estimated from the critical micelle concentration and the apparent degree of counterion attachment. For sodium dodecyl sulfate, NA = 162(Y,q)1/4 is pred...
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The spin densities of the nitroxides H 2 N O , (CH 3 )HNO and (CH 3 ) 2 NO have been studied by iterative CI methods. Calculations at different geometries with various basis sets were performed. It is found that the spin distribution is delocalized within the N O group, and substitution of the hydrogen atoms on the nitroxyl group by methyl groups changes the spin distribution significantly. Ele...
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ژورنال
عنوان ژورنال: Bulletin of the Chemical Society of Japan
سال: 1979
ISSN: 0009-2673,1348-0634
DOI: 10.1246/bcsj.52.980